Abstract
Theoretical basis and methodology for calculation and modeling of ozonation processes and contact equipment have been elaborated. Methodology of determination of reaction rate constant, stoichiometric coefficient, optimum values of pH, intermediate and final products, regimes of chemisorption, etc., for certain typical fast and slow reacting organic compounds (aniline, toluidine, humic acids, nitrobenzene, glyoxalic, oxalic and acetic acid) and wastewaters have been proposed. For calculation of the wastewater ozonation process, the value of chemical oxygen demand (COD) was suggested to be as a kinetic parameter from the solution side. On the basis of kinetic information, recommendations for the choice of the construction of contact equipment for the different chemisorption regimes of ozonation have been presented. Some new contact apparatuses have been proposed.