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Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 15, 1993 - Issue 2
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Original Articles

Methodology Of Ozone Introduction Into Water And Wastewater Treatment

Pages 149-165 | Received 28 Apr 1991, Accepted 07 Oct 1992, Published online: 23 Jul 2008
 

Abstract

Theoretical basis and methodology for calculation and modeling of ozonation processes and contact equipment have been elaborated. Methodology of determination of reaction rate constant, stoichiometric coefficient, optimum values of pH, intermediate and final products, regimes of chemisorption, etc., for certain typical fast and slow reacting organic compounds (aniline, toluidine, humic acids, nitrobenzene, glyoxalic, oxalic and acetic acid) and wastewaters have been proposed. For calculation of the wastewater ozonation process, the value of chemical oxygen demand (COD) was suggested to be as a kinetic parameter from the solution side. On the basis of kinetic information, recommendations for the choice of the construction of contact equipment for the different chemisorption regimes of ozonation have been presented. Some new contact apparatuses have been proposed.

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