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Journal of Dispersion Science and Technology Volume 29, 2008 - Issue 2
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Original Articles

The Calculation of Interfacial Tension and Electrostatic Free Energy of Spherical Ionic Micelles with High Surface Potentials

Genxiang Luo Department of Chemistry, College of Petrochemical Engineering, Liaoning University of Petroleum and Chemical Technology, Fushun, Liaoning, P. R. ChinaCorrespondence[email protected]
,
Qingdao Wang Vocational & Technology College, Liaoning University of Petroleum & Chemical Technology, Fushun, Liaoning, P. R. China
&
Haoping Wang Department of Chemistry, College of Petrochemical Engineering, Liaoning University of Petroleum and Chemical Technology, Fushun, Liaoning, P. R. China
Pages 257-260 | Received 04 Jan 2007, Accepted 20 Jan 2007, Published online: 31 Jan 2008
 
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Based on extended Langmuir's method on the dressed micelles, approximate expressions for the calculation of interfacial tension and electrostatic free energy of spherical ionic micelles with high surface potentials have been presented. These expressions are derived from nonlinear Poisson‐Boltzmann equation. The present formulae for the calculation of interfacial tension and electrostatic free energy of spherical ionic micelles are in quite good agreement with Hayter's results.

We are grateful to the National Science Foundation of China (NSFC) for financial support No. 20273028.

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