Effect of Octadecanol on the Interfacial Dilational Properties of Surfactant/Polymer Systems

Abstract

The effect of octadecanol on dilational properties of 4,5-diheptyl-2-propylbenzene sulfonate and partly hydrolyzed polyacrylamide at the decane-water interface has been examined by means of longitudinal method. The octadecanol plays different roles in influencing the structure of adsorbed layers at different bulk concentration. A small quantity of octadecanol may enhance the dilational modulus by forming densely packed mixed-adsorption layer with surfactant molecules through hydrophobic interaction, which leads to the increase of dilational modulus. However, due to the weakening of the “entanglement” among long alkyl chains in surfactant molecules by the intercalation of octadecanol, the superfluous addition of octadecanol could decrease the dilational modulus. In the case of polymer/octadecanol system, the addition of the polymer may enhance the dilational modulus due to the slow diffusion-exchange process of the polymer.

Keywords:

• 4,5-Diheptyl-2-propylbenzene sulfonate
• dilational modulus
• dilational phase angle
• HPAM
• interface
• octadecanol

The authors are thankful for the financial support from the National Science and Technology Major Project (2008ZX05011) and National High Technology Research and Development Program (2008AA092801) of China.