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Journal of Dispersion Science and Technology Volume 32, 2010 - Issue 1
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Original Articles

Synthesis and Properties of Nanocomposites with Silver/Alternating Copolymers (Divinylbenzene-Maleic Anhydride)

Dan Donescu Polymer Department, National Institute of Chemical and Petrochemical Research and Development-ICECHIM, Independence Street, Bucharest, Romania
,
Marius Ghiurea Polymer Department, National Institute of Chemical and Petrochemical Research and Development-ICECHIM, Independence Street, Bucharest, Romania
,
Raluca Somoghi Polymer Department, National Institute of Chemical and Petrochemical Research and Development-ICECHIM, Independence Street, Bucharest, RomaniaCorrespondence[email protected]
,
Sever Serban Polymer Department, National Institute of Chemical and Petrochemical Research and Development-ICECHIM, Independence Street, Bucharest, Romania
&
Cristian Petcu Polymer Department, National Institute of Chemical and Petrochemical Research and Development-ICECHIM, Independence Street, Bucharest, Romania
Pages 120-124 | Received 10 Sep 2009, Accepted 06 Nov 2009, Published online: 20 Dec 2010
 
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Abstract

Nanocomposites of divinylbenzene-maleic anhidride (DVB-MA) copolymers were synthesized in aqueous medium by generating silver nanoparticles from AgNO3-NaBH4 reaction. SEM images evidence the forming of metal nanoparticles on the particles surface of DVB-MA copolymers. The copolymer particles have larger diameters in the presence of monoesther maleic of nonyl phenol ethoxylate or sodium montmorillonite than DVB-MA copolymer particles although the nanoparticles' forming is still possible. The average size and the Zeta potential of the hybrid particles decrease in water, toward the initial copolymers sustains the forming of nanocomposites with Ag nanoparticles on the surface.

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