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Journal of Dispersion Science and Technology Volume 37, 2016 - Issue 8
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Original Articles

Intrinsic Rheo-Kinetics on Gelation Process of Hydrophobic Amphoteric Cellulose

Ming MaLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
,
Bo FangLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, ChinaCorrespondence[email protected]
,
Yongjun LuLangfang Filial of Research Institute of Petroleum Exploration and Development, Petro China, Langfang, China
,
Meng TianLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
,
Xiaohui QiuLangfang Filial of Research Institute of Petroleum Exploration and Development, Petro China, Langfang, China
,
Guodong LiLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
,
Hao JinLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
,
Yuwei HeLDS Technology Co., LTD., Beijing, China
,
Caihe HuangLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
,
Yuting LiuLangfang Filial of Research Institute of Petroleum Exploration and Development, Petro China, Langfang, China
,
Liwei WangLangfang Filial of Research Institute of Petroleum Exploration and Development, Petro China, Langfang, China
&
Kejing LiLaboratory of Chemical Engineering Rheology, Research Center of Chemical Engineering, East China University of Science and Technology, Shanghai, China
 show all
Pages 1076-1082 | Received 25 Jul 2015, Accepted 04 Aug 2015, Published online: 16 Mar 2016
 
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Abstract

Micro-rheological properties including elasticity index (EI) and solid liquid balance (SLB) of gelation process of hydrophobic amphoteric cellulose solution at different temperatures and crosslinker concentrations were investigated by optical micro-rheometer in this work. During the crosslinking gelation process, EI appears a two-stage rise, and SLB first increases to maximum and then decreases to constant. According to EI curves, the gelation process can be divided into two stages. Intrinsic rheo-kinetics equations were first established to characterize the two-stage crosslinking process. The simulated values by the novel intrinsic rheo-kinetic models were in good agreement with experimental data and the model parameters were well-defined and of reasonable significance.

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