AFM study on the wettability of mica and graphite modified with surfactant DTAB

ABSTRACT

In this work atomic force microscopy (AFM) was applied to study the wettability of mica and graphite modified with surfactant dodecyltrimethylammonium bromide (DTAB) at varying DTAB concentrations (below the cmc) and adsorption time. The coverage states of DTAB on surfaces were analyzed from the AFM images, while the contact angle measurement was made for the wettability of DTAB-modified surfaces. The experimental results have shown that the adsorption aggregates formed as needle-like dots covering on the mica surface with the surfactant concentration of 10⁻⁶–10⁻⁴ mol/L. The coverage of DTAB aggregates increased with the increasing concentration, leading to a strong hydrophobicity on the surfaces. However, the large aggregates which might be caused by bilayer adsorption of surfactant occurred on mica surface at surfactant concentration of 10⁻³ mol/L, resulting in the reverse of the wettability as the adsorption time extended. In the case of hydrophobic graphite, DTAB aggregates mainly formed as stripe covering on the surfaces, leading to the reduction of hydrophobicity. This reduction became stronger as more DTAB aggregates covered on graphite surfaces.

GRAPHICAL ABSTRACT

KEYWORDS:

• Adsorption
• AFM
• surface coverage
• surfactant
• wettability

Additional information

Funding

The financial support to this work provided from the National Natural Science Foundation of China (numbers 51674183 and 51504174) is gratefully acknowledged.