Immobilization of C/Ce-codoped ZnO nanoparticles on multi-walled carbon nanotubes for enhancing their photocatalytic activity

Abstract

C/Ce-codoped ZnO nanoparticles immobilized onto multi-walled carbon nanotubes (C/Ce-ZnO@MWCNT) were successfully fabricated via the hydrothermal method for degradation of methylene blue (MB) under visible light irradiation. The prepared C/Ce-ZnO@MWCNT samples were characterized by XRD, XPS, FTIR, FE-SEM, EDX, BET, and diffuse reflectance spectroscopy. The obtained results indicated that the photocatalytic activity of all the MWCNTs-containing samples was higher than those of the bare ZnO and C/Ce-codoped ZnO nanoparticles. Besides, the C/Ce-ZnO@MWCNT composite with 50 wt% MWCNT showed the highest photocatalytic activity with the MB removal efficiency of 96.5% recorded within 90 min under visible light illumination using 1.0 g/L catalyst dosage at pH of 9 and MB concentration of 30 ppm. The degradation mechanism controlled by the charge transfer process in C/Ce-ZnO@MWCNT composite was proposed and discussed in detail. In addition, the long-term-use ability of the photocatalyst was also evaluated through experiments conducted in continuous cycles.

Graphical Abstract

Keywords:

• C/Ce-ZnO@MWCNT
• photocatalytic activity
• methylene blue
• visible light
• multi-walled carbon nanotube