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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 9, 1990 - Issue 3-4
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Original Articles

Studies on the Mixed Trimeric Reaction of Schiff Bases and Structures of Related Metal Complexes

Xiu-Ren Bu Coordination Chemistry Institute. Nanjing University, Nanjing, People's Republic of China
,
Xiao-Zeng You Coordination Chemistry Institute. Nanjing University, Nanjing, People's Republic of China
&
Qing-Jin Meng Coordination Chemistry Institute. Nanjing University, Nanjing, People's Republic of China
Pages 221-244 | Published online: 23 Sep 2006
 
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Abstract

An efficient and direct method for the syntheses of new double Schiff bases by reactions of two different aldehydes and ammonia have been developed. These reactions have also been extended to obtain some novel types of ferrocene derivatives. Specific catalytic hydrolysis of double Schiff bases by metallic ion through intramolecule axial coordination was ascertained. The ESR characteristic of hydrolytic products in solution is discussed, and some crystal structures of new metal complexes are reported.

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