Solvothermal fabrication of TiO₂ nanosheet films on degradable Mg–Zn alloys

Abstract

Anatase TiO₂ nanosheet films were fabricated on Mg–Zn alloy substrates through a special solvothermal method, aiming to improve the corrosion resistance of degradable Mg–Zn alloy stents. In this novel synthesis process, absolute alcohol was used as solvent, and small amounts of hydrofluoric acid and NH₄F aqueous solution were used to adjust the hydrolysis rate of titanium precursors and the crystal morphology of anatase TiO₂, respectively. The NH₄F played a key role in the growth of TiO₂ nanosheets by supplying fluorine ions (F⁻). The anatase TiO₂ films had a compact surface consisting of interleaving nanosheets with thickness of about 50 nm. In simulated body fluids, the corrosion current density (I_corr) of Mg–Zn alloy substrates decreased from 789.5 to 24.4 µA cm⁻², after being coated with the TiO₂ nanosheet films.

Keywords:

• Solvothermal
• Mg–Zn alloy
• Anatase TiO₂
• Nanosheet films
• Corrosion resistance

Acknowledgement

This work was supported by National Natural Science Foundation of China (No. 51171174/E0113).