ABSTRACT
The changes of the structure, microscopic morphology of electrodeposited Ni–Sn–P alloys before and after heat treatment in nitrogen were studied by means of X-ray diffraction and scanning electron microscopy. The corrosion behaviour was analysed by electrochemical impedance spectroscopy, anodic polarisation curves and potentiostatic polarisation corrosion. The results show that as the heat-treatment temperature increase, the structure of Ni–Sn–P alloy changed from amorphous to crystalline and the corrosion resistance of which decreased correspondingly. When the heat-treatment temperature was lower than 400°C, the electrodeposited Ni–Sn–P alloys remained amorphous structure and exhibited better corrosion resistance than that of electroless Ni–P coating in acidic medium.
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