Rayleigh scattering of a new lyotropic nematic liquid crystal system: crossover of propagative and diffusive behaviour

Abstract

In this paper we present to our knowledge the first light-scattering measurements on a rather new lyotropic system potassium laurate, decylammonium chloride, H₂O. Relative concentrations were chosen in order to obtain the discotic N_D phase over a large temperature range. Measurements involve digital recording of the autocorrelation function resulting from selfbeating of the depolarized scattered light. They were carried out at a fixed temperature in the N_D phase range, by varying the scattering angle. A strong tendency to oscillations, superimposed on the usual relaxation signal, was found. This behaviour is quite surprising, as special precautions had been taken to minimize any eventual propagative signal. Such precautions have been tested previously, while investigating the older system potassium laurate, decanol, D₂O. Nevertheless, we have found that in the new lyotropic system, a propagative component may occur in a significant way, or even become dominant for some particular situations. Actually, the characterization of such situations is the main purpose of the present paper. Based upon a detailed analysis of photocorrelation data, it will be shown that the observed behaviour is consistent with the expected wave vector dependences of propagative and diffusive modes. Finally, a discussion is given on possible causes for the tendency to instability of lyotropic nematic liquid crystals.