Spacer length dependence of TGBC* and SmA phases in cholesteryl and dihydrocholesteryl‐containing trimer liquid crystals

Abstract

Two series of trimer liquid crystals were investigated that contain a biphenylyl central group and two cholesteryl or dihydrocholesteryl terminal mesogenic groups. Only compounds with even spacers were investigated. The dihydrocholesteryl‐containing trimers show a triply intercalated smectic A (SmA) phase when the spacer lengths are greater than 8, whereas the cholesteryl‐containing trimers exhibit this triply intercalated SmA phase when the spacer lengths are more than 6. With shorter spacers, a twist grain boundary C* (TGBC*) phase was found. This is revealed by the formation of a typical dotted square grid pattern upon cooling from the chiral nematic (N*) phase in the planar texture. The dots are spaced by a distance of about 1.5–1.8 µm. Upon cooling from the N* phase in the focal conic texture a striped pattern is observed with the same spacing. X‐ray diffraction revealed a repeat distance for the TGBC* phase that corresponds with a monolayer ordering. The results show that the weaker interaction between the dihydrocholesteryl groups compared with cholesteryl groups or longer spacers destabilize the monolayer TGBC* phase.

Acknowledgements

The syntheses of several new compounds were performed by undergraduate students Jurriaan Bakker, Martine Bokma, Linda Klauss and Niels ten Brummelhuis.