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Original Articles

Photoswitching of holographic polymer‐dispersed liquid crystals doped with chiral dopant

, , , &
Pages 1115-1120 | Received 11 Jul 2007, Accepted 10 Aug 2007, Published online: 08 Oct 2007
 

Abstract

Chiral dopants were added to the formulation of holographic polymer‐dispersed liquid crystals and the effects studied in terms of grating formation dynamics, morphology, diffraction efficiency, contrast ratio and electro‐optical properties of the films. A gradual increase of real‐time diffraction efficiency, decrease of droplet size and increase of diffraction efficiency of the composite film were obtained with the addition and increasing content of chiral dopant, due to the increased viscosity of the liquid crystal (LC) doped with the chiral dopant leading to decreased droplet coalescence. The contrast ratio decreased with increasing content of chiral dopant due to the difficult orientation of LC molecules caused by the formation of a helical structure. Addition of a small amount of the chiral dopant increased the driving voltage slightly, whereas the decay time is decreased significantly as a result of the high twisting of the helical structure.

Acknowledgements

This research has been supported by the NCRC organized at PNU (No. R15‐2006‐022‐01002‐0).

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