Abstract
In this study, a single-layer polymer-stabilised liquid crystal (PSLC) film reflecting both right- and left-circularly polarised light has been developed by a wash-out/refill method. A polymer network/liquid crystals (LCs) composite, in which the polymer network had a certain helical structure, was prepared by photo polymerisation of the photo-polymerisable LC monomers (LCMs) in a LCM/LC/photoinitiator mixture. Then, the LC molecules were extracted from the composite film and cholesteric LCs (Ch-LCs) with the opposite helical structure were refilled into the film. The film was constructed by the polymer network with a certain helical structure and Ch-LCs with the opposite helical structure could reflect both right- and left-circularly polarised light simultaneously. The reflection intensity of the film is close to 100% when the pitch lengths of the two opposite helical structures are the same, which goes beyond the 50% reflectance limit of Ch-LCs. It was demonstrated that the memory effect of the polymer network is an important mechanism for the resulting film properties.
Acknowledgement
This research was supported by the National Natural Science Foundation (grant nos. 50903004 and 50673007).