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Invited Articles

Liquid crystalline imidazolium salts bearing 5-phenylpyrimidine: dependence of mesomorphic properties on spacer lengths, terminal N-alkyl group and counterions

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Pages 1515-1529 | Received 16 Jun 2011, Accepted 01 Aug 2011, Published online: 22 Nov 2011
 

Abstract

New imidazolium salts bearing substituted 5-phenylpyrimidine mesogenic groups were synthesised and their mesomorphic properties were studied by differential scanning calorimetry, optical microscopy and powder X-ray diffraction methods (WAXS, SAXS). The parent 5-phenylpyrimidines with the terminal bromide group at the alkoxy spacer exhibited low clearing points and smectic mesophases in narrow temperature ranges. The incorporation of the N-alkylimidazolium cationic core, connected with 5-phenylpyrimidine via an alkoxy spacer, remarkably improved the stability of the mesophases. The imidazolium salts with 5-phenylpyrimidine group formed smectic A phases, stable over broad temperature intervals. The influences of the counteranion, the length of terminal alkyl group and alkoxy spacer on the mesomorphic behaviour of the 5-phenylpyrimidine substituted N-alkylimidazolium salts were investigated in detail.

Acknowledgement

Generous financial support by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, the Ministerium für Wissenschaft, Forschung und Kunst des Landes Baden-Württemberg, the Bundesministerium für Bildung und Forschung (BMBF shared instrumentation grant 01RI05177), the Gesellschaft Deutscher Chemiker (grant for G.F.S.) and the International Max-Planck-Research School for Advanced Materials (fellowship for M.K.) is gratefully acknowledged.

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