The complete morphological, electro-optical and dielectric study of dichroic dye-doped polymer-dispersed liquid crystal

Abstract

Polymerisation-induced phase separation method was used to prepare dye-doped polymer-dispersed liquid crystal (DPDLC) films consisting of nematic liquid crystal, photo-curable pre-polymer and a dichroic dye. The change occurring on droplets morphology with the change in dye concentration and voltage was investigated by means of polarising optical microscope and scanning electron microscope. Electro-optic behaviour of these composite films in the presence of an externally applied AC electric field (0–100 V, 200 Hz) and temperature range 25–50°C was evaluated using He–Ne laser. The maximum absorbance of dye and effect of electric field on the absorbance of dye was studied using UV-Vis spectrophotometer. Dielectric relaxation spectroscopy was carried out in the frequency range 20 Hz–20 MHz and over the temperature range 25°C–90°C. Dielectric parameters such as distribution parameter, relaxation frequency, relaxation strength and relaxation time of these DPDLC films were calculated, and the modelling of experimental data was done using Debye and Cole–Cole method.

Keywords:

• DPDLC
• electro-optical
• dielectric relaxation spectroscopy
• Cole–Cole plot

Acknowledgements

Authors thank Manoj Malik and Sanmesh Parab for their support during experimental work.

Funding

Anuja Katariya Jain would like to thank the University Grants Commission (UGC), India for financial assistance through UGC-SAP programme. This work was supported by the [AICTE, India] under [grant number 8023/BOR/RID/RPS-05/9/10].