ABSTRACT
Novel C2-symmetric chiral dopant derivatives, namely, N-substituted (2R, 3R)-2,3-bis(4-(4-octyloxyphenyl)benzoyloxy)succinimides1a-h, were synthesised, and the effects of the N-substituent and imide-carbonyl groups on the helical twisting powers (HTPs) were investigated in two nematic liquid crystalline compounds, 4-n-pentyl-4ʹ-cyanobiphenyl (5CB) and N-(4-ethoxybenzylidene)-4-n-butylaniline (EBBA). As a result, it was clarified that the bulkiness of the N-substituents has a significant correlation with the HTPs, and the imide-carbonyl group interacts strongly with the cyano group of 5CB to give high HTPs in the nematic phases. However, it is assumed that the imide-carbonyl groups of the dopants do not have strong electrostatic attractive interactions with EBBA molecules in the nematic phase to afford the moderate HTPs.
Graphical Abstract
![](/cms/asset/08d02081-043f-4ef6-bfd0-6602c8c295c3/tlct_a_1255361_uf0001_oc.jpg)
Acknowledgements
We thank Dr. Ozaki who saved KK’s life by an operation for brain haemorrhage during the term of this project.
Disclosure statement
No potential conflict of interest was reported by the authors.
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