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Articles

Non-covalent intermolecular interactions of colloidal nematic liquid crystals doped with graphene oxide

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Pages 1341-1355 | Received 27 Jul 2016, Accepted 28 Dec 2016, Published online: 09 Jan 2017
 

ABSTRACT

Graphene oxide (GO) was doped to eutectic uniaxial nematic liquid crystals (NLCs) (E5CN7) with different percentages to improve the physiochemical properties of NLCs effectively. GO shifts the N-I phase transition temperature to higher values. It has been observed that increasing GO concentration up to 0.75% increases the N-I phase transition temperature substantially while further increase of GO concentration results in an inverse trend. The GO/E5CN7 non-covalent interactions change the N-I phase transition. The contribution of several terms such as anchoring and polarisation effects on N-I phase transition was quantified as well. The results suggest that the size is an important contributor to GO and liquid crystal interaction. The results show that E5CN7@GO composites may act as promising candidates to enhance the efficiency of room temperature devices.

GRAPHICAL ABSTRACT

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