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Original Articles

The Thermotropic Liquid-Crystalline Properties of Some Straight Chain Carbohydrate Amphiphiles

, , , &
Pages 1569-1581 | Received 16 Dec 1987, Accepted 07 Mar 1988, Published online: 06 Nov 2007
 

Abstract

A variety of homologous 1-deoxy-1-(N-methylalkamido)-D-glucitols were prepared and their liquid crystal phases characterized. In this study the thermotropic liquid-crystalline properties of these materials are investigated. The mesophases formed are shown to be of the smectic A class with an interdigitated bilayer ordering of the constituent molecules. This ordering is thought to be stabilized by hydrogen-bonding between neighbouring carbohydrate moieties. The properties of these materials are compared with those of other closely related acyclic carbohydrates.

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