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Original Articles

Molecular theory of smectic C liquid crystals

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Pages 399-409 | Received 14 Aug 1995, Accepted 13 Oct 1995, Published online: 24 Sep 2006
 

Abstract

We generalize an earlier density functional theory of liquid crystals by Mederos and Sullivan. The original theory took account of anisotropic hard core interactions, and for suitable intermolecular interactions predicted nematic and smectic A phases as well as isotropic liquid and vapour phases. In this generalization we also take into account quadrupolar or dipole induced dipole interactions. The modified theory now also predicts the existence of a smectic C phase.

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