Morphological and chemical characteristics of atmospheric particles in the Metropolitan Zone of Toluca Valley (Mexico)

Abstract

Scanning electron microscopy with energy-dispersive spectroscopy has been used for both morphological and elemental chemistry analyses of atmospheric particles. This technique allows the in situ observation of individual aerosol particles in the sample chamber. Aerotransported particles were analysed from seven monitoring stations located in the Metropolitan Zone of Toluca Valley (MZTV). Several different morphologies were identified: aggregates, porous spheres, rough and smooth compact material. The elemental composition included C, Na, Mg, Al, Si, S, Cl, K, Mn, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn and Ce. These are semiquantitative analyses considering the bulk sample or individual particles. It was possible to correlate or confirm some chemical associations such as C–S, Ca–S–O and Si–Al–O, probably due to the presence of compounds derived from incomplete combustion, building tailing materials and aluminosilicates of cortical origin. Bioaerosols such as pollen, spores, brochosomes and diatoms were identified in the zone; all these types of particles have a natural origin too. Several types of suspended particles were identified in the MZTV, they were from different sources (natural and anthropogenic) to which the population can be potentially exposed, and may cause harm in the short- and long-term, according to their chemical element composition and size.

Keywords:

• PM ₁₀
• Metropolitan Zone of Toluca Valley
• aerosols
• bioaerosols
• air pollution
• SEM–EDS
• emission sources

Acknowledgements

We are grateful to the COMECYT EDOMEX-2005-CO-01-09 financial support. The authors wish to thank RAMAT personal, Q.F.B. Alejandra López Tinoco, Q. Carlos Edgardo Aguirre Campuzano, T. Rodrigo Sandoval Castañeda, T. Ricardo Rodríguez and Vidal Morales Mercado. We wish to thank to Dr. Marcos José Solache Ríos and Kathleen Keller from Digerati Networks, USA for the English revision of the manuscript and M. en EB Liliana Romero Guzmán for her technical help.