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Environmental Chemistry/Technology

Effects of β-cyclodextrin on adsorption and desorption of carbofuran in soils of divergent texture

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Pages 1613-1622 | Received 18 Jan 2011, Accepted 28 May 2011, Published online: 26 Jul 2011
 

Abstract

Laboratory studies were conducted to determine the adsorption/desorption equilibrium of carbofuran between four divergently textured soils and distilled water and an aqueous solution of 0.01 mol L−1 β-cyclodextrin using a batch equilibrium technique. The determined adsorption isotherms for silt loam soils were of L-shaped, for sandy loam soil S-shaped, in agreement with a Freundlich isotherm. In the presence of β-cyclodextrin, the adsorption of carbofuran to the four soils was lower than with distilled water. Positive hysteresis was observed in all soils with distilled water, negative hysteresis when using a solution of β-cyclodextrin as desorbent. The results indicate the potential use of β-cyclodextrin for remediation of pesticide-contaminated soils.

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