Separate Bleaching of Pulp Fractions Enriched in Earlywood and Latewood Fibers

Abstract

Unbleached softwood kraft pulp was fractionated in hydrocyclones into a fine fraction, enriched in earlywood fibers, and a coarse fraction, enriched in latewood fibers. The response to individual bleaching chemicals and the bleachability in bleaching sequences of the pulp fractions was studied.

The light absorption coefficient, light scattering coeffient, and brightness were higher in the unbleached fine fraction than in the coarse fraction. Hydrogen peroxide managed to reduce the light absorption coefficient of the earlywood enriched fine fraction more efficiently than that of the latewood enriched fraction.

In the TCF‐sequence the light absorption coefficient of the fine fraction was reduced to the level of the coarse fraction at a given consumption of bleaching chemicals. In the ECF‐sequence the difference in light absorption coefficient remained between the fractions. At a given consumption of bleaching chemicals, the fine fraction had higher brightness than the coarse fraction, 2%‐ and 1%‐units on the ISO‐scale in the TCF and ECF bleaching sequence, respectively.

Keywords:

• Softwood
• bleaching response
• latewood fibers
• earlywood fibers
• hydrocyclone
• fractionation

The authors express their thanks to Rose Marie Karlsson for skilful experimental work and to Elisabet Bergnor‐Gidnert for fruitful discussions. The thanks is also extended to VINNOVA (Swedish Governmental Agency for Innovation Systems) and the project steering group with the participating companies; AssiDomän, Billerud, Fiber Tracker, GL&V, Kemira, Korsnäs, and Metso.