ABSTRACT
This work provides an environmental approach to utilise Blast furnace slag (BFS) waste for the processing of aluminium oxide (Al2O3-BFS) as an efficient adsorbent for uranium removal from wastewater. The composition of BFS is less variable and this makes it a low cost and abundant raw material for preparing a solid base Al2O3-BFS. The silica material was initially removed and then the aluminium content was separated by precipitation with sodium hydroxide depending on pH control (pH 5.5). The raw BFS and Al2O3-BFS were characterised via various methods, such as; XRD, Zeta potential, N2 adsorption-desorption isotherm, DLS, and FT-IR. BFS exhibited the typical type III isotherm with an H3-type hysteresis loop. The curve of Al2O3-BFS exhibited the typical IV isotherms with a H2-type hysteresis loop. The BET surface and average pore sizes of the Al2O3-BFS are 137.7 m2 g-1 and 3.9 nm, respectively. Experiments and discussions were performed in terms of balance, isothermal, kinetic, and applicability. The finding provides proof of the ability of synthesised Al2O3-BFS to remove U(VI) ions from wastewater as an efficient adsorbent with a maximum sorption capacity value of 62 mg/g. The pseudo second, Langmuir and Dubinin-Radushkevich models were found suitable to explain the rate kinetics and isotherm of uranium removal. Uranium sorption on Al2O3-BFS may occur via inner-sphere complex and ion-exchange between uranium ions and HO-Al2O3-BFS groups. The higher elution efficiency of Al2O3-BFS indicates a promising adsorbent in the technology of U(VI) removal.
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Acknowledgments
The authors acknowledge Taif University Researchers Supporting Project number (TURSP-2020/05), Taif University, Taif, Saudi Arabia.
Disclosure statement
No potential conflict of interest was reported by the authors.