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Original Articles

ETUDE DE LA REACTIVITE DE QUELQUES PHOSPHOR(III)ADAMANTANES

, , , &
Pages 105-119 | Received 02 Jul 1982, Published online: 13 Dec 2006
 

Abstract

A new phosphor(III)adamantan has been synthesized. The reactivity of that compound and of other phosphor(III)adamantans has been investigated. New phosphazens and new spirophosphorans have been obtained. The weak reactivity of these phosphor(III)adamans can be explained in terms of hybridization of the phosphorus free electron pair.

Un nouveau phosphor(III)adamantane a été synthétisé. La réactivité de ce composé et celle de quelques autres phosphor(III)adamantanes ont été étudiées. De nouveaux phosphazènes et de nouveaux spirophosphoranes ont pu ětre obtenus. La faible réactivité de ces phosphor(III)adamantanes peut ětre expliquée par l'hybridation du doublet libre du phosphore.

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