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Original Articles

REACTIONS OF DIPHENYL PHOSPHINE OXIDE WITH DIACETYL AND ETHYL PYRUVATE

Pages 39-42 | Received 25 Feb 1985, Accepted 21 Mar 1985, Published online: 13 Dec 2006
 

Abstract

3-Hydroxy-3-diphenyloxophosphino-butanone-2 and 2-hydroxy-2-diphenyloxophosphino-propionic acid ethyl ester were synthesized by reacting diphenyl phosphine oxide with diacetyl or ethyl pyruvate respectively. The reaction of diphenyl phosphine oxide with diacetyl did not lead to an addition to both carbonyls of diacetyl although the reactants ratio utilized was 2:1. The structure of the aforementioned compounds was confirmed by elemental analysis. IR and 1H-NMR spectroscopy.

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