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Polymer-Plastics Technology and Engineering Volume 49, 2010 - Issue 8
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Original Articles

Modification of Epoxy Resin by Cyanate Ester Resin and Liquid Butadiene-Acrylonitrile Rubbers

Xudong Sun Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, P.R. China; Graduate University of Chinese Academy of Science, Beijing, P.R. China; Institute of Applied Chemistry, Shaoxing University, Shaoxing, P.R. China
,
Minfeng Zeng Institute of Applied Chemistry, Shaoxing University, Shaoxing, P.R. China
,
Cuiyun Lu Institute of Applied Chemistry, Shaoxing University, Shaoxing, P.R. China
,
Fengyuan Yan Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, P.R. China; Graduate University of Chinese Academy of Science, Beijing, P.R. China
&
Chenze Qi Institute of Applied Chemistry, Shaoxing University, Shaoxing, P.R. ChinaCorrespondence[email protected]
Pages 772-778 | Published online: 07 Jul 2010
 
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Abstract

In this paper, the results showed that the addition of an appropriate amount of reactive rubbers ((ie: carboxyl randomized butadiene-acrylonitrile rubber (CRBN) and hydroxyl terminated butadiene-acrylonitrile rubber (HTBN)) to epoxy resin/cyanate ester resin (EP/CE) (70/30) improved both the mechanical properties and thermal stability of the resulting blends. CRBN and HTBN have different reactive activity and dispersion state in EP/CE/rubbers. No drop in the thermal stability of the EP/CE network with addition of these two rubber component is related to the low rubber concentrate and the reactions between the rubbers and EP or CE.

ACKNOWLEDGMENTS

This work was supported by National Natural Science Foundation of China (grant number: 10875079), and Natural Science Foundation of Zhejiang Province, China (grant number: Y4080448).

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