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Polymer-Plastics Technology and Engineering Volume 51, 2012 - Issue 5
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Original Articles

Synthesis, Electrochemical Behaviors and Anion Recognition of A Novel Star-[Polystyrene-b-poly(ferrocenyloxy ethyl acrylate)]6 with Hexafunctional Cyclotriphosphazene Core

Anguo Xiao Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, ChinaCorrespondence[email protected]
,
Zhijun Li Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
,
Shibiao Zhou Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
,
Qingyun Zheng Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
,
Youming Shen Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
,
Zhengan Chen Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
,
Weiqing Zheng Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
&
Aiping Hao Department of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde, Hunan, China
 show all
Pages 521-525 | Published online: 16 Apr 2012
 
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Abstract

A novel star-[polystyrene-b-poly(ferrocenyloxy ethyl acryl ate)]6 with hexa- functional cyclotriphosphazene core (star-(PS-b-PFcEA)6) was synthesized by atom -transfer radical polymerization(ATRP) and its electrochemical behaviors and anion recognition was investigated through CV. The results indicated that increasing of molecular weight resulted in obvious decreasing of reduction peak potential Epc, and the oxidation peak potential Epa kept comparatively stable. Moreover, when titrating anion into polymer solution, Epc increased while Epa reduced evidently, which suggested that star-(PS-b-PFcEA)6 provided with high anion recognition capacity of .

Notes

a CuBr:CuBr2: PMDETA: FcEA: macroinitiator = 1:0.1:1.1:20:1, [FcEA] = 0.05 M,using star-(PS)6 as macroinitiator).

a [Fe]: 1.0 mM; [Bu4N]BF4: 0.1 M; scan rates: 0.15 v/s.

a [Fe]:1.0 mM; [Bu4N]BF4: 0.1 M; scan rates:0.15 v/s.

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