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Polymer-Plastics Technology and Engineering Volume 52, 2013 - Issue 13
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Original Articles

The Influence of 2-Hydroxyethyl Acrylate on the Properties of Cationic Poly(VAc-BA-HEA) Terpolymer Latexes

Xu Meng Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, China; Graduate University of Chinese Academy of Sciences, Beijing, China
,
Gang Peng Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, China; Graduate University of Chinese Academy of Sciences, Beijing, China
,
Bin Wang Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, China; Graduate University of Chinese Academy of Sciences, Beijing, China
,
Bailing Liu Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, ChinaCorrespondence[email protected]
,
Rong Luo Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, China
,
Hualin Chen Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, China
,
Zhibao Dong Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou, China
,
Yuan Li Research Institute of Sinopec Sichuan Vinylon Plant, Chongqing, China
,
Wei Ning Research Institute of Sinopec Sichuan Vinylon Plant, Chongqing, China
,
Bo Zhang Research Institute of Sinopec Sichuan Vinylon Plant, Chongqing, China
&
Lihua Luo Research Institute of Sinopec Sichuan Vinylon Plant, Chongqing, China
 show all
Pages 1323-1329 | Published online: 30 Sep 2013
 
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Abstract

The cationic poly(vinyl acetate-butyl acrylate-2-hydroxyethyl acrylate) terpolymer latexes (Poly(VAc-BA-HEA)) were successfully prepared using the emulsion polymerization. The structure and composition, morphology, and thermal property of the latexes were characterized by FTIR, TEM and DSC, respectively. Also, the correlations between the particle size, zeta potential, viscosity and water absorption of prepared cationic latexes and 2-hydroxyethyl acrylate concentration were established. The results show that the concentration of 2-hydroxyethyl acrylate could affect the properties of the latexes significantly. This offers an attractive opportunity for adjusting the particle size and viscosity of latexes over a wide range by feeding 2-hydroxyethyl acrylate with varying concentration.

ACKNOWLEDGMENTS

The authors gratefully acknowledge the ‘‘Western Light'’ of Chinese Academy of Sciences and the Sichuan Vinylon Corporation (Chongqing, China) for providing the financial support.

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