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Polymer-Plastics Technology and Engineering Volume 56, 2017 - Issue 10
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Original Articles

Synergistic Flame-retardant Effect and Mechanism of Nitrogen–Phosphorus-Containing Compounds for Glass Fiber-reinforced Polyamide 66

Wenhua ChenState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
,
Pengju LiuState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
,
Yuansen LiuEngineering Research Center of Marine Biological Resource Comprehensive Utlization, Third Institute of Oceanography, State Oceanic Administration, Xiamen, China
,
Yuan LiuState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, ChinaCorrespondence[email protected]
&
Qi WangState Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Pages 1118-1127 | Published online: 07 Apr 2017
 
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ABSTRACT

The system based on aluminum phosphinate (OP) and melamine polyphosphate was applied in flame-retardant glass fiber-reinforced polyamide 66. From a qualitative and quantitative point of view, the incorporation of OP played a positive role in obtaining the homodisperse of flame-retardant particles throughout the composites. A two-step cooling mode during the degradation process was established to play an effective role in absorbing heat to retard the flame spread rate and provide enough time for barrier generation. In condensed phase, the cross-linked structure formed in residue promoted the construction of the high-quality barrier layer.

GRAPHICAL ABSTRACT

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