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Polymer-Plastics Technology and Engineering Volume 57, 2018 - Issue 10
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Original Articles

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Zehra YildizDepartment of Polymer Science and Technology, Institute of Sciences and Technology, Istanbul Technical University, Istanbul, Turkey;Department of Textile Engineering, Faculty of Technology, Marmara University, Istanbul, Turkey;School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USAView further author information
,
Hacer Aysen OnenDepartment of Chemistry, Faculty of Arts and Sciences, Istanbul Technical University, Istanbul, TurkeyCorrespondence[email protected]
View further author information
,
Atilla GungorDepartment of Chemistry, Faculty of Arts and Sciences, Istanbul Technical University, Istanbul, TurkeyView further author information
,
Youjiang WangSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USAView further author information
&
Karl JacobSchool of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USAView further author information
Pages 935-944 | Published online: 03 Oct 2017
 
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ABSTRACT

A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.

GRAPHICAL ABSTRACT

Additional information

Funding

This study has been financially supported by Istanbul Technical University Research Fund and The Scientific and Technological Research Council of Turkey (TUBITAK).

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