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Original Articles

Palladium-Mediated Cyclization on Carbohydrate Templates. 3. Extension of The Cyclization to the Threo Series.

Pages 221-232 | Published online: 27 Feb 2008
 

ABSTRACT

The palladium(0)-catalyzed Heck-type cyclization-β-alkoxy elimination reaction leading to enantiopure bicyclic compounds in the case of erythro 2,3-unsaturated glycosides has been successfully extended to the threo stereoisomer by only changing the aglycon moiety from an ethoxy group to an aryloxy moiety.

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