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Journal of Carbohydrate Chemistry Volume 32, 2013 - Issue 2
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Original Articles

Facile Diastereoselective Synthesis of Carbohydrate-Based Thiochromans

Henok H. Kinfe Department of Chemistry, University of Johannesburg, Auckland Park, 2006, South Africa
,
Paseka T. Moshapo Department of Chemistry, University of Johannesburg, Auckland Park, 2006, South Africa
,
Felix L. Makolo Department of Chemistry, University of Johannesburg, Auckland Park, 2006, South Africa
&
Alfred Muller Department of Chemistry, University of Johannesburg, Auckland Park, 2006, South Africa
Pages 139-157 | Received 31 Jul 2012, Accepted 20 Dec 2012, Published online: 12 Feb 2013
 
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Abstract

An efficient and novel diastereoselective thiochroman synthesis using the carbohydrate chiral pool via intramolecular Friedel-Crafts alkylation is presented. The scope and limitations of the method are investigated.

ACKNOWLEDGMENT

We thank the University of Johannesburg for financial support and Prof. CW Holzafel for valuable discussions and advice on this manuscript.

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