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Journal of Carbohydrate Chemistry Volume 37, 2018 - Issue 3
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Articles

Glycosyl hydroperoxides

Barbara SzechnerInstitute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, Poland
,
Barbara GrzeszczykInstitute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, Poland
,
Bartłomiej FurmanInstitute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, Poland
&
Marek ChmielewskiInstitute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, PolandCorrespondence[email protected]
Pages 104-116 | Received 29 Dec 2017, Accepted 27 Jan 2018, Published online: 08 Mar 2018
 
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GRAPHICAL ABSTRACT

ABSTRACT

The present mini-review concentrates on glycosyl hydroperoxides readily available from sugars, such as 2-deoxy glycosides, 2,3-unsaturated glycosides and glycals, prone to acidic hydrolysis. They represent an interesting, relatively stable family of monosaccharide derivatives of potential antimalarial activity, which can also be used for effective enantioselective epoxidation of allylic alcohols and electrophilic olefins.

Acknowledgements

Financial support by the European Union within European Regional Development Fund, Project POIG.01.01.02.-14-102/09 is gratefully acknowledged.

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