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Nucleosides and Nucleotides Volume 11, 1992 - Issue 2-4
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Original Articles

Pummerer Rearrangement of Selenium-Containing Uracil Nucleosides

Kazuhiro Haraguchi School of Pharmaceutical Sciences, Showa University, Hatanodai 1-5-8, Shinagawa-ku, Tokyo, 142, Japan
,
Shigeru Saito School of Pharmaceutical Sciences, Showa University, Hatanodai 1-5-8, Shinagawa-ku, Tokyo, 142, Japan
,
Hiromichi Tanaka School of Pharmaceutical Sciences, Showa University, Hatanodai 1-5-8, Shinagawa-ku, Tokyo, 142, Japan
&
Tadashi Miyasaka School of Pharmaceutical Sciences, Showa University, Hatanodai 1-5-8, Shinagawa-ku, Tokyo, 142, Japan
Pages 483-493 | Received 31 Aug 1991, Accepted 07 Nov 1991, Published online: 23 Sep 2006
 
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Abstract

Pummerer-type rearrangement of uracil nucleosides having a phenylseleno group in the 2′-, 3′-, and 5′-positions took place upon oxidation with MCPBA in CH2Cl2 followed by treatment with acid anhydrides to yield α-acyloxyselenides.

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