Abstract
The (+)-enantiomer of the carbocyclic analogs of the four 2′-deoxyribonucleoside monophosphate constituents of DNA, C-dAMP2 (1: A), C-dGMP (1: G), C-dCMP (1: C), and C-TMP (1: T) have been synthesized via the Mitsunobu coupling reaction. Two new N3-protected thymines were developed en route.