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Nucleosides and Nucleotides Volume 17, 1998 - Issue 6
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Original Articles

Terminal Fluoroolefins. The Synthesis of Novel Carboacyclic Nucleosides

Shawn C. Miller Hoechst Marion Roussel Inc., 2110 East Galbraith Rd., Cincinnati, OH, 45215
,
James R. McCarthy Hoechst Marion Roussel Inc., 2110 East Galbraith Rd., Cincinnati, OH, 45215
&
Jeffrey S. Sabol Hoechst Marion Roussel Inc., 2110 East Galbraith Rd., Cincinnati, OH, 45215
Pages 1099-1113 | Published online: 21 Aug 2006
 
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Abstract

A facile preparation of ketone 7 from butanetriol acetonide 5 is reported, and its utility for the synthesis of novel carboacyclic nucleosides 3E, 3Z, 4E and 4Z by the selective manipulation of multiple functionalities is demonstrated.

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