Advanced search
Publication Cover
Solvent Extraction and Ion Exchange Volume 18, 2000 - Issue 2
Submit an article Journal homepage
120
Views
41
CrossRef citations to date
0
Altmetric
Original Articles

STUDY OF THE SORPTION OF Cr(III) WITH XAD-2 RESIN IMPREGNATED WITH DI-(2,4,4 TRIMETHYLPENTYL)PHOSPHINICACID (CYANEX 272)

R. Navarro Mendoza Instituto de Investigaciones Científicas. Universidad de Guanajuato, Cerro de la Venada, Guanajuato, Gto, 36040, México;View further author information
,
T. I. Saucedo Medina Instituto de Investigaciones Científicas. Universidad de Guanajuato, Cerro de la Venada, Guanajuato, Gto, 36040, México;
,
A. Vera Instituto de Investigaciones Científicas. Universidad de Guanajuato, Cerro de la Venada, Guanajuato, Gto, 36040, México;
,
M. Avila Rodríguez Instituto de Investigaciones Científicas. Universidad de Guanajuato, Cerro de la Venada, Guanajuato, Gto, 36040, México;
&
E. Guibal Instituto de Investigaciones Científicas. Universidad de Guanajuato, Cerro de la Venada, Guanajuato, Gto, 36040, México;
Pages 319-343 | Received 20 Jan 1999, Published online: 10 May 2007
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

ABSTRACT

Solvent impregnated resin containing Cyanex 272 (di-(2,4,4-trimethylpentyl)phosphinic acid, denoted HL) was prepared by adsorption of the organophosphorus extractant into the polymeric macroporous support Amberlite XAD-2. The extraction of Cr(III) from nitrate solution at 0.1 ionic strength by the impregnated resin has been studied at 25°C The sorption of the metal ion was studied as a function of both pH and extractant concentration in the resin phase. The impregnated resin shows good affinity towards the extraction of Cr(III). The best sorption efficiency (98%) was obtained at pH≈5. A thermodynamic model is proposed for modeling the distribution data. This model shows that Cr(III) is extracted as Cr(OH)(HL)2(N03) 2 and Cr(OH)L2. The elution of the metal from the resin was accomplished (95%) with 6.0 M HCI. The elution treatment allows the impregnated resin to be reused.

Additional information

Notes on contributors

R. Navarro Mendoza

To whom correspondence should be addressed.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

EQUILIBRIUM DISTRIBUTION OF PALLADIUM(I I) BETWEEN HYDROCHLORIC ACID SOLUTION AND A MACROMOLECULAR RESIN CONTAINING TRI-n-OCTYLAMINE
Source: Informa UK Limited
Approach of uranium sorption mechanisms on chitosan and glutamate glucan by IR and l3C-NMR analysis
Source: Elsevier BV
Application of ionic liquids in the preparation of extraction chromatographic materials for metal ion separations: Progress and prospects
Source: Informa UK Limited
Column-mode separation and pre-concentration of some heavy metal ions by solvent-impregnated resins containing quinizarin before the determination by flame atomic absorption spectrometry
Source: Informa UK Limited
Metal Sorption by Materials with a Mobile Phase of Extractants
Source: Pleiades Publishing Ltd
Isothermal, kinetic, and thermodynamic studies for solid-phase extraction of uranium (VI) via hydrazine-impregnated carbon-based material as efficient adsorbent
Source: Springer Science and Business Media LLC
Enhancement of Metal Ion Sorption Performances of Chitosan: Effect of the Structure on the Diffusion Properties
Source: American Chemical Society (ACS)
Solvent-impregnated resins containing di-(2,4,4-trimethylpentyl) phosphonic acid I. Comparative study of di-(2,4,4-trimethylpentyl)phosphinic acid adsorbed into Amberlite XAD-2 and dissolved in toluene
Source: Elsevier BV
Novel Environmental Sorbents and Methods for their Characterization
Source: Springer Netherlands
Liquid-liquid extraction separation of iron (III) with 2-ethyl hexyl phosphonic acid mono 2-ethyl hexyl ester
Source: Elsevier BV
METAL COMPLEXES WITH PHOSPHONIC AND PHOSPHINIC ACIDS
Source: Walter de Gruyter GmbH
Immobilization of extractants in biopolymer capsules for the synthesis of new resins: a focus on the encapsulation of tetraalkyl phosphonium ionic liquids
Source: Royal Society of Chemistry (RSC)
Distribution equilibria in the adsorption of cobalt(II) and nickel(II) on Levextrel resin containing Cyanex 272
Source: Elsevier BV
Tri-n-octylamine impregnated Seplite LX-16 resin for extraction of U(VI) from sulfate medium
Source: Springer Science and Business Media LLC
Solvent impregnated resins containing Cyanex 272. Preparation and application to the extraction and separation of divalent metals
Source: Elsevier BV
Uptake of uranyl ions by new sorbing polymers: discussion of adsorption isotherms and pH effect
Source: Elsevier BV
UPTAKE OF METAL IONS BY A NEW CHELATING ION EXCHANGE RESIN. PART 8 : SIMULTANEOUS UPTAKE OF CATIONIC AND ANIONIC SPECIES* *
Source: Informa UK Limited
Solvent extraction of iron (III) by bis (2,4,4-trimethylpentyl) phosphinic acid: experimental equilibrium study
Source: Elsevier BV

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.