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Solvent Extraction and Ion Exchange Volume 29, 2011 - Issue 4
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Original Articles

Dependence of Extraction Properties of 2,6-Dicarboxypyridine Diamides on Extractant Structure

M. Yu. Alyapyshev Khlopin Radium Institute, St. Petersburg, RussiaCorrespondence[email protected]
,
V. A. Babain Khlopin Radium Institute, St. Petersburg, RussiaCorrespondence[email protected]
,
L. I. Tkachenko Khlopin Radium Institute, St. Petersburg, Russia
,
I. I. Eliseev Khlopin Radium Institute, St. Petersburg, Russia
,
A. V. Didenko Department of Organic Chemistry, St. Petersburg State Technological Institute, St. Petersburg, Russia
&
M. L. Petrov Department of Organic Chemistry, St. Petersburg State Technological Institute, St. Petersburg, Russia
Pages 619-636 | Published online: 18 Jul 2011
 
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Abstract

New diamides of dipicolinic acid have been prepared and their affinity for lanthanides, americium, and uranium has been explored using the liquid-liquid extraction method. These extractants feature mixed alkyl/aryl substituents. The highest extraction is seen for phenyl/ethyl derivatives. The structure-reactivity relationship for extraction and solubility is discussed.

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