Optimization and Single-Stage Centrifugal Contactor Experiments with the Novel Hydrophilic Complexant PyTri-Diol for the i-SANEX Process

ABSTRACT

The applicability of 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl)]pyridine (PyTri-Diol) in the innovative Selective ActiNide EXtraction (i-SANEX) process as water-soluble complexing agent was studied. Preliminary batch experiments were aimed at identifying the optimal formulation of the PyTri-Diol solution and at preparing the ground for single-stage centrifugal contactor experiments. A N,N,N′,N′ tetraoctyl diglycolamide (TODGA)-based solvent loaded using a spiked synthetic Plutonium and Uranium Reduction EXtraction raffinate and the optimized PyTri-Diol aqueous phase were contacted in a single-stage annular centrifugal contactor setup with three different flow-rate conditions. No hydrodynamic problems were encountered, and promising minor actinide separation from other cations was achieved with satisfactory kinetics and stage efficiency. The flow sheet of a TODGA–PyTri-Diol-based i-SANEX process was designed exploiting batch and single-stage data, promoting the CHON compliant PyTri-Diol as excellent alternative to the formerly used SO₃–Ph–BTP.

KEYWORDS:

• Partitioning
• i-SANEX
• PyTri ligand
• TODGA
• single-stage centrifugal contactor

Additional information

Funding

This work has been supported by the EU-FP7 SACSESS project: [Grant Number 323282], EU-H2020 GENIORS project: [Grant number 755171], and the Italian Ministry of Education, University and Research.