Abstract
Oxygen isotope measurements have played a key role in establishing the way the solar system has formed. On Earth mass-dependent fractionation constrains conditions under which oxygen distributes itself among different phases. In the solar system, oxygen can experience kinetic fractionation as well, but the predominant cosmochemical signature is variability in 16O. This was first recognised in refractory inclusions, the oldest known materials in the solar system, where 4% excesses in 16O were apparent. Subsequently the range has increased to nearly 50% with the extreme values being an 8% excess of 16O (relative to terrestrial oxygen) in a chondrule, and to an apparent deficit in 16O of 40% in chondrite matrix. Originally interpreted as a nucleosynthetic signature, these compositions appear to be due to photochemical speciation either in the solar system or the precursor molecular cloud.
Acknowledgements
This work has benefitted from discussions over the years with Hisayoshi Yurimoto, Ko Hashizume and Kevin McKeegan. Reviews of this manuscript by Hisayoshi Yurimoto, Doug Rumble and anonymous reviewer are gratefully acknowledged. This work would not have been possible without Marc Norman's efforts in putting this volume together. Some of the work included here was supported by ARC Discovery Grants (DP0342772 and DP0666751).