LIQUID PHASE OXIDATION OF HEXYLDISULFIDE BY t-BUTYL HYDROPEROXIDE IN BENZENE

George W. Mushrush Navy Technology Center for Safety & Survivability Fuels Section, The Naval Research Laboratory, Code 6180, Washington, D.C, 20375-5000

Robert E. Pellenbarg Navy Technology Center for Safety & Survivability Fuels Section, The Naval Research Laboratory, Code 6180, Washington, D.C, 20375-5000

Robert N. Hazlett Navy Technology Center for Safety & Survivability Fuels Section, The Naval Research Laboratory, Code 6180, Washington, D.C, 20375-5000

Dennis R. Hardy Navy Technology Center for Safety & Survivability Fuels Section, The Naval Research Laboratory, Code 6180, Washington, D.C, 20375-5000

ABSTRACT

There are inconsistencies in the literature regarding the role of organosulfur compounds in general, and sulfonic acids in particular, on the oxidative instability of middle distillate fuels. Comparison of published results between investigations is complicated by differences in a large number of variables. Variations in fuel composition, heteroatam distribution, reaction surface, hydroperoxide concentration, dissolved oxygen and reaction temperature all contribute to the variation in observed results. In an effort to clarify this situation, we have examined the t-butyl hydroperoxide liquid phase oxidation of hexyldisulfide in deaerated benzene.

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LIQUID PHASE OXIDATION OF HEXYLDISULFIDE BY t-BUTYL HYDROPEROXIDE IN BENZENE

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LIQUID PHASE OXIDATION OF HEXYLDISULFIDE BY t-BUTYL HYDROPEROXIDE IN BENZENE

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