ELECTRON TRANSFER MECHANISMS IN OXIDATIVE SEDIMENT FORMATION IN FUELS. II. AN ELECTROCHEMICAL INVESTIGATION OF THE COUPLING BETWEEN PERINAPHTHENE AND INDOLE.

Claude P. Andrieux Laboratoire d'Electrochimie Moleculaire, Université Paris 7, Unité Associée au CNRS n° 438, 2 Place Jussieu 75251, Paris, Cedex 05, France.

Monique Gareil1 Laboratoire d'Electrochimie Moleculaire, Université Paris 7, Unité Associée au CNRS n° 438, 2 Place Jussieu 75251, Paris, Cedex 05, France.

Jean Pinson Laboratoire d'Electrochimie Moleculaire, Université Paris 7, Unité Associée au CNRS n° 438, 2 Place Jussieu 75251, Paris, Cedex 05, France.

Didier Martin Eff France, Centre de Recherche de Solaize, Saint Symphorten d'Ozon, France.

ABSTRACT

Cyclic voltammetry and electrolyses in acetonitrile and toluene have indicated the formation of coupling products between perinaphthene and indole similar to those found in the oxidized sediments of fuels. The formation of these coupling products involves intermediates which are one electron oxidized species. This paper discusses the possible mechanisms by which these products are formed.| Photochemical experiments were performed by irradiating the pyrex electrochemical cell with a 300 W tungsten lamp.

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ELECTRON TRANSFER MECHANISMS IN OXIDATIVE SEDIMENT FORMATION IN FUELS. II. AN ELECTROCHEMICAL INVESTIGATION OF THE COUPLING BETWEEN PERINAPHTHENE AND INDOLE.

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ELECTRON TRANSFER MECHANISMS IN OXIDATIVE SEDIMENT FORMATION IN FUELS. II. AN ELECTROCHEMICAL INVESTIGATION OF THE COUPLING BETWEEN PERINAPHTHENE AND INDOLE.

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