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Original Articles

CHEMICAL ANALYSIS OF HIGH ASH BRAZILIAN COAL TAR. 3. HYDROCARBON CHARACTERIZATION

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Pages 427-450 | Published online: 25 Apr 2007
 

Abstract

In this paper we show the total analysis of the hydrocarbon fractions obtained from the chromatographic fractionation of a coal tar cut, previously described. All fractions were analyzed by Gas Chromatography coupled to Mass Spectrometry using a non-polar capillary column. A group-type distribution of aliphatic, olefins and monoaromatic hydrocarbons was found in the first three fractions obtained (I, II and III). In fractions IV and V polyaromatics with two or more condensed rings were founded. Many of these hydrocarbons are recognized to be carcinogenic and mutagenic, including pyrene, chrysene and others.

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