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High Pressure Research
An International Journal
Volume 29, 2009 - Issue 4: PROCEEDINGS OF THE XLVIITH EUROPEAN HIGH PRESSURE RESEARCH GROUP (EHPRG 47) MEETING, PARIS (FRANCE), 6–11 SEPTEMBER 2009
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Spectroscopy and transitions

Pressure-induced phase transition of ice in aqueous KOH solution

Yukihiro Yoshimura Department of Applied Chemistry, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa, 239-8686, JapanCorrespondence[email protected]
Pages 542-547 | Received 31 Aug 2009, Published online: 15 Dec 2009
 
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Abstract

The changes in situ in Raman spectra of ice in aqueous KOH solution as a function of pressure at liquid nitrogen temperature (77 K) have been examined. The possibility that the ice in aqueous KOH directly transforms to the low-temperature ice IX phase at around 1 GPa, not via high-density amorphous ice, is shown. Also, it is reported that the results show differences strongly depend on the salts dissolved in the aqueous solutions.

Acknowledgements

The author would like to acknowledge Dr R.J. Hemley for useful discussions and Y. Muramatsu for providing experimental assistance.

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