Ruby fluorescence lifetime measurements for temperature determinations at high (p, T)

Abstract

The lifetime of the ruby R₁ fluorescence line was measured as a function of pressure (up to about 20 GPa) and temperature (550 K) in an externally heated diamond anvil cell (DAC). At constant temperatures, the lifetime is increasing linearly with increasing pressure. The slope of the pressure dependence is constant up to a temperature of 450 K and it is decreasing at higher temperatures. At constant pressure, the lifetime is exponentially decreasing with increasing temperature. The (p, T)-dependence can be parametrized by the combination of a linear and an exponential function. This allows an accurate p, T-determination by the combination of fluorescence spectroscopy using Sm²⁺-doped strontium tetraborate and lifetime measurements of ruby, as the energy of the Sm²⁺ fluorescence is nearly temperature-independent.

Keywords:

• high pressure and temperature
• fluorescence lifetime
• diamond anvil cell

Acknowledgements

Financial support from Deutsche Forschungsgemeinschaft (German Research Foundation, DFG) under grant WI1232/ 25-2 within SPP1236 is gratefully acknowledged.