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High Pressure Research
An International Journal
Volume 35, 2015 - Issue 3
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Articles

Zr-based bulk metallic glass as a cylinder material for high pressure apparatuses

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Pages 254-262 | Received 27 Jan 2015, Accepted 14 Apr 2015, Published online: 12 May 2015
 

Abstract

Zirconium-based bulk metallic glass (Zr-based BMG) has outstanding properties as a cylinder material for piston-cylinder high pressure apparatuses and is especially useful for neutron scattering. The piston-cylinder consisting of a Zr-based BMG cylinder with outer/inner diameters of 8.8/2.5 mm sustains pressures up to 1.81 GPa and ruptured at 2.0 GPa, with pressure values determined by the superconducting temperature of lead. The neutron attenuation of Zr-based BMG is similar to that of TiZr null-scattering alloy and more transparent than that of CuBe alloy. No contamination of sharp Bragg reflections is observed in the neutron diffraction pattern for Zr-based BMG. The magnetic susceptibility of Zr-based BMG is similar to that of CuBe alloy; this leads to a potential application for measurements of magnetic properties under pressure.

Acknowledgements

We are grateful to Dr H. Yoshida (UTokyo) for the electron micro probe analysis, Drs T. Hattori (JAEA), A. Sano-Furukawa (JAEA), S. Harjo (JAEA), J. Abe (CROSS), H. Arima (Tohoku Univ.), M. Arakawa (Kyusyu Univ.), and R. Iizuka (Univ. of Bayreuth) for their help with the neutron attenuation measurements (J-PARC proposal no. 2009A0082) and also Drs A. Nakao (CROSS) and T. Ohhara (JAEA) for their help with the neutron diffraction experiments at SENJU in J-PARC (J-PARC proposal no. 2013I0108).

Disclosure statement

No potential conflict of interest was reported by the authors.

Funding

This study was supported by JSPS KAKENHI [grant number 19GS0205], [grant number 20103001-4], [grant number 25870182], [grant number 26246039]. Research conducted at ORNL's High Flux Isotope Reactor was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy. This study was supported in part by the US-Japan Cooperative Program on Neutron Scattering.

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