Boron-doped diamond synthesized by chemical vapor deposition as a heating element in a multi-anvil apparatus

ABSTRACT

We tested boron-doped diamond (BDD) synthesized by chemical vapor deposition (CVD) as a heating element in a multi-anvil apparatus. We succeeded in manufacturing BDD into a tubular shape by laser cutting and electric discharging machining. The BDD tube shaped by the electric discharging machining was contaminated by discharging electrode materials (Mo and W), which affected the heating performance. The laser-cut BDD tube has a clean surface and, therefore, had a good heating performance. We succeeded in generating temperature as high as 2670 K at a pressure around 30 GPa with laser-cut heater. Heating reproducibility was confirmed through repeated heating and cooling cycles. The recovered sample shows that a higher temperature generation above 2670 K was prevented by eutectic melting of ZrO₂ thermal insulator and Al₂O₃ sample. Owing to the commercial availability with a reasonable price, CVD–BDD heaters are more practical than a high-pressure synthesized BDD heaters for wide applications.

KEYWORDS:

• Chemical vapor deposition
• boron-doped diamond
• multi-anvil apparatus
• high-temperature generation
• X-ray transparency

Acknowledgements

The authors thank T. Boffa Ballaran, K. Vlasov, L. Dubrovinsky, F. Heidelbach, S. Khandarkhaeva, A. Kurnosov, T. Meier, for their help on using the electric discharging machine. We would like to thank R. Njul, and D. Wiesner for their help on polishing sample and measuring SEM, respectively. The authors thank Fang Xu, Chao Wang, Hongzhan Fei, Biao Wang, Takayuki Ishii, Yingwei Fei for constructive discussions.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (Grant agreement No. 787 527, UltraLVP).