Preparation of thermally stable organic-inorganic hybrid nanocomposites from chemically functionalized oxidized graphite by in situ catalytic oxidative decarboxylation

ABSTRACT

In this study, the preparation of thermally stable organic-inorganic hybrid nanocomposites from chemically functionalized oxidized graphite is carried out by in-situ catalytic oxidative decarboxylation of 3,5-dinitrobenzoic acid (reactant) in the presence of potassium persulfate (oxidant), silver nitrate (catalyst) and graphite (support) under thermal or microwave conditions. The effects of heat transfer and dosages of reactant, catalyst and oxidant on the crystalline structure and the morphology of nanocomposites are studied in detail. The prepared nanocomposites are characterized by EDS, elemental mapping, FE-SEM, FT-IR and XRD. The thermal stability of nanocomposites is examined by TGA and DSC. EDS shows that nanocomposites are composed of C, O, N, S, K and Ag elements. FT-IR exhibits that the graphitic layers in nanocomposites are mainly oxidized and functionalized with carboxyl, carbonyl, hydroxyl, epoxy, sulfate, nitrate and nitroaryl groups. Addition of nitroaryl groups to nanocomposites is also supported by an increase found in their C and N contents. XRD demonstrates the coexistence of both oxidized amorphous carbon and graphite in combination with different levels of organic and inorganic phases. The prepared nanocomposites show good thermal stability. The total area of the DSC curve in these nanocomposites compared to graphite is enhanced.

Graphical abstract

KEYWORDS:

• Nanocomposite
• graphite
• catalytic oxidative decarboxylation
• carbon-carbon bond formation
• thermal stability

Author contributions

Zahra Shareh: Investigation, Formal analysis. Mehdi Zamani: Conceptualization, Methodology, Validation, Formal analysis, Resources, Data Curation, Writing – Original Draft, Writing – Review & Editing, Visualization, Supervision, Project administration, Funding acquisition.

Disclosure statement

No potential conflict of interest was reported by the authors.

Supplementary data

Supplemental data for this article can be accessed online at https://doi.org/10.1080/09276440.2023.2200600.

Additional information

Funding

We would like to thank the research committee of Damghan University for funding and supporting this work.