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Philosophical Magazine Letters Volume 96, 2016 - Issue 11
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Original Articles

Absolute asymmetric electrochemical polymerization

Hiromasa GotoDivision of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, JapanCorrespondence[email protected]
Pages 409-415 | Received 17 Jul 2016, Accepted 26 Sep 2016, Published online: 11 Oct 2016
 
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Abstract

Electrochemical polymerization of thiophene-based achiral monomer having azobenzene as a chromophore irradiated by circular polarized light (CPL) was carried out to obtain chiroptically active polymer film on indium-tin oxide-coated glass. Circular dichroism and optical absorption spectroscopy measurements indicate the samples show chiroptical activity. This result indicates occurrence of absolute asymmetric polymerization by laser CPL.

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